Volume 499
Main Index

Issues 1-2, Pages 1-260 (6 September 1995)

Editorial Board Page iii

Hideki Sakurai Pages vii-x Mitsuo Kira

Subject index of volume 499 Pages C12-C17

Author index of volume 499 Pages C10-C11

Et3GeNa---YCl3 complex as a new strong base Pages C4-C6 Yasuo Yokoyama, Kunio Mochida

Palladium-tert-alkyl isocyanide catalyzed intramolecular bis-silylation of vicinally disubstituted alkenes Pages C1-C3 Michinori Suginome, Akira Matsumoto, Koichi Nagata, Yoshihiko Ito

Synthesis, solid-state structure, and reduction of 1,1-dichloro-2,3,4,5-tetramethylsilole Pages C7-C9 Uwe Bankwitz, Honglae Sohn, Douglas R. Powell, Robert West

Photolysis of some organosilylene precursors in a molecular beam Pages 1-5 Yuhui Huang, Mark Sulkes, Mark J. Fink

The dimethylaminoethyl-tetramethylcyclopentadienyl ligand in germanium(II) chemistry: synthesis, properties and X-ray crystal structural data of (Me2NCH2CH2) Me4C5GeCl Pages 7-10 Peter Jutzi, Holger Schmidt, Beate Neumann, Hans-Georg Stammler

The positions of λmax for some trimethylsilyl-substituted silylenes Pages 11-16 S. G. Bott, Paul Marshall, P. E. Wagenseller, Y. Wang, R. T. Conlin

1 : 2-adducts from silylenes and 1,3-butadiene Pages 17-26 Kevin L. Bobbitt, Peter P. Gaspar

Redox properties of dihalogermylenes, dihalostannylenes and their complexes with Lewis bases Pages 27-34 V. Ya. Lee, A. A. Basova, I. A. Matchkarovskaya, V. I. Faustov, M. P. Egorov, O. M. Nefedov, R. D. Rakhimov, K. P. Butin

Silicon-carbon unsaturated compounds LIV: Nickel-catalyzed reactions of 3,4-benzo-1,1,2,2-tetraethyl-1,2-disilacyclobut-3-ene with alkynes Pages 35-41 Akinobu Naka, Shougo Okazaki, Masaki Hayashi, Mitsuo Ishikawa

Synthesis and reactions of stanneneselone Pages 43-48 Masaichi Saito, Norihiro Tokitoh, Renji Okazaki

Protonated digermyl and distannyl ethers with partial germylium and stannylium ion character Pages 49-55 Joseph B. Lambert, Sol M. Ciro, Charlotte L. Stern

Rates of solvolysis of the compounds (Me3Si) 2(Ph2MeSi) CSiMe2X, X = I, OSO2 CF3 and OCN. Mechanistic implications Pages 57-62 Mohammad A. M. R. Al-Guarashi, G. Adefikayo Ayoko, Colin Eaborn, Paul D. Lickiss

Interactions in crystals. LXXXIII. The structures of 1,2,4,5-tetrakis(trimethylsilyl)benzene and of its solvent-separated radical anion salt [Na(H3COCH2CHn2OCH3)3] [((H3C)3Si)4H2C6·] Pages 63-71 Hans Bock, Manssur Ansari, Norbert Nagel, Zdenek Havlas

Synthesis and the electronic spectra of the first ß-ketoacylsilanes and their lithium enolates: new insights into hyperconjugation in acylsilanes and their enolates Pages 73-82 Yitzhak Apeloig, Ilya Zharov, Dmitry Bravo-Zhivotovskii, Yuri Ovchinnikov, Yuri Struchkov

Generation and reactions of metal-free trialkylgermyl anions from silylgermane and digermane Pages 83-88 Kunio Mochida, Hiroyasu Suzuki, Michihiko Nanba, Tsuyoshi Kugita, Yasuo Yokoyama

Synthesis and characterization of sterically hindered diarylsilanes containing 2,4,6-trimethylphenyl and 2,4,6-tris(trifluoromethyl)phenyl substituents. X-ray crystal structure of bis[2,4,6-tris(trifluoromethylphenyl)]fluorosilane Pages 89-98 Janet Braddock-Wilking, Matt Schieser, Lee Brammer, Jean Huhmann, Raef Shaltout

Decomposition of bis(silyldiazomethyl) polysilanes: formation of polysilabicyclo[1.m.n]alkane derivatives Pages 99-111 Wataru Ando, Mitsuru Sugiyama, Tomohisa Suzuki, Chikako Kato, Yusuke Arakawa, Yoshio Kabe

Synthesis and characterization of 1,9-difluoro-5-methyl-5-phenyl-10,11-dihydro-5H-dibenzo[b,f]silepin Pages 113-121 Joyce Y. Corey, Alexander J. Pitts, Rudolph E. K. Winter, Nigam P. Rath

Electronic properties, polymerization, and cycloaddition of 3,4,7,8-tetragermacycloocta-1,5-diyne and related compounds Pages 123-129 Haruhiko Komoriya, Masahiro Kako, Yasuhiro Nakadaira, Kunio Mochida, Mari Tonogaki-Kubota, Tsunetoshi Kobayashi

Tetrakis (perfluoropropyl)tin and other perfluoropropyltin compounds: Synthesis, characterization and reactivity Pages 131-136 Dietmar Seyferth, Frank Richter

Nucleophile-assisted racemizations of halosilanes: thermodynamic studies Pages 137-141 Alan R. Bassindale, Juliana C. -Y. Lau, Peter G. Taylor

Synthesis and crystal structure of a pentacoordinate 1,2-oxagermetanide Pages 143-146 Takayuki Kawashima, Yuri Nishiwaki, Renji Okazaki

Intramolecular coordination at phosphorus: donor-acceptor interaction in three- and four-coordinated phosphorus compounds Pages 147-154 Francis Carré, Claude Chuit, Robert J. P. Corriu, Pascal Monforte, Naresh K. Nayyar, Catherine Reyé

Ene preference in the reaction of allenylmethylsilanes with hetero-double bonds mediated by a Lewis acid Pages 155-157 Makoto Hojo, Chikara Murakami, Hidenori Aihara, Kyoji Tomita, Katsukiyo Miura, Akira Hosomi

Aluminum chloride catalyzed stereo- and regiospecific allylsilylation of alkynes: a convenient route to silyldienes Pages 159-165 Seung Ho Yeon, Joon Soo Han, Eunkee Hong, Youngkyu Do, Il Nam Jung

Catalytic asymmetric hydrosilylation of 1,3-dienes with difluoro(phenyl) silane Pages 167-171 Hideaki Ohmura, Hayao Matsuhashi, Makoto Tanaka, Manabu Kuroboshi, Tamejiro Hiyama, Yasuo Hatanaka, Ken-ichi Goda

The role of dioxygen in hydrosilylation of alkenes catalyzed by ruthenium phosphine complexes Pages 173-179 Jacek Guliski, Brian R. James, Bogdan Marciniec

Reactions of silanes with allylic alcohols catalyzed by titanocene derivatives: an approach to catalytic cross dehydrocoupling/co-intramolecular hydrosilation Pages 181-191 Shixuan Xin, John F. Harrod

Co2(CO)8-catalyzed reaction of aromatic aldehydes with hydrosilanes under carbon monoxide as 1 atm: Incorporation of CO into the carbonyl carbon atom of aldehydes Pages 193-197 Naoto Chatani, Hideo Tokuhisa, Ichiro Kokubu, Satoru Fujii, Shinji Murai

Synthesis of new poly(2,4-disilapentane) oligomers via dehydrocondensation reaction using Group IV metallocene catalysts Pages 199-204 Philippe Roux, Jean-Paul Pillot, Marc Birot, Jacques Dunoguès, P. Lapouyade

Redistribution reactions of hydrosilanes mediated by the unsymmetrical and homometallic phosphido-bridged complex (η5-C5Me5)Fe2(CO)4( μ-CO)(μ-PPh2) Pages 205-211 Hisako Hashimoto, Hiromi Tobita, Hiroshi Ogino

Activation of a C---O bond by reaction of a tris(cyclopentadienyl)lanthanide complex with an alkali metal in dimethoxyethane (DME); crystal structures of [Ndη-C5H3(SiMe3)2-1,32(μ-OMe)2Li(DME)] and [{Ce(η-C5H3tBu2-1,3)2(μ-OMe)2] Pages 213-219 Yurii K. Gun'ko, Peter B. Hitchcock, Michael F. Lappert

Synthesis, structures, and properties of novel aminodisilanes bearing bulky substituents: 1,2-bis(1,1,2-trimethylpropyl)-1,1,2,2-tetrakis(diethylamino) disilane and 1,2-di-tert-butyl-1,1,2,2-tetrakis(diethylamino) disilane Pages 221-228 Masafumi Unno, Mina Saito, Hideyuki Matsumoto

The different modes of decomposition of hexa-t-butylcyclotrisilane Pages 229-234 Manfred Weidenbruch, Edwin Kroke, Siegfried Pohl, Wolfgang Saak, Heinrich Marsmann

Hepta-tert-butylcyclotetrasilane: a highly crowded cyclotetrasilane Pages 235-240 Soichiro Kyushin, Haruaki Sakurai, Hideyuki Matsumoto

Syntheses, structures and properties of dihydroxypermethylcyclosilanes and permethyloxahexasilanorbornanes Pages 241-246 A. Spielberger, P. Gspaltl, H. Siegl, E. Hengge, K. Gruber

Synthesis, structure, and reactivity of the permethylated decasilane (Me3Si)3Si---SiMe2---SiMe2---SiMe3)3 Pages 247-252 Stephen M. Whittaker, Mari-Carmen Brun, Francisco Cervantes-Lee, Keith H. Pannell

Synthesis and characterization of polystyrene-block-poly(methylphenylsilylene) and polyisoprene-block-poly(methylphenylsilylene) Pages 253-260 Eric Fossum, Jonathan A. Love, Krzysztof Matyjaszewski